How are you planning to broadcast this then? Full run, or cut out the filler/random encounters? Personally, I think a Pokemon LP is never really good idea for its sheer length and fairly roamy style. It's a decent enough start though, if a little short, and the character boards are a nice touch. You have a rather humorous speaking style as well, was quite nice to listen to. Best of luck with it.
P.S. "Pokémon Mento"?
There are three things I try to live by:
1) Never tell a bride the day before her wedding day that "there is a problem"
2) Nothing good happens after 2AM - just go to bed.